Name | 4-hexen-3-one |
Synonyms | FEMA 3352 NSC 245483 4-hexen-3-one 4-HEXEN-3-ONE 4-HEXENE-3-ONE hex-4-en-3-one (E)-hex-4-en-3-one (4Z)-hex-4-en-3-one (4E)-hex-4-en-3-one Hexen-3-one, predoMinantly 4-Hexen-3-one,predominantly trans |
CAS | 2497-21-4 |
EINECS | 219-681-2 |
InChI | InChI=1/C6H10O/c1-3-5-6(7)4-2/h3,5H,4H2,1-2H3/b5-3+ |
Molecular Formula | C6H10O |
Molar Mass | 98.14 |
Density | 0.858 g/mL at 25 °C (lit.) |
Melting Point | -71.05°C (estimate) |
Boling Point | 135-137 °C (lit.) |
Flash Point | 94°F |
JECFA Number | 1125 |
Vapor Presure | 6.71mmHg at 25°C |
Specific Gravity | 0.855 |
Storage Condition | Sealed in dry,Room Temperature |
Refractive Index | n20/D 1.44(lit.) |
MDL | MFCD00010631 |
Physical and Chemical Properties | Colorless to light yellow liquid. Boiling point 136~137 deg C. Relative density (d420)0.8537, refractive index (nD20)1.4385. |
Hazard Symbols | Xn - Harmful |
Risk Codes | R10 - Flammable R22 - Harmful if swallowed R36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S16 - Keep away from sources of ignition. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
UN IDs | UN 1224 3/PG 3 |
WGK Germany | 3 |
RTECS | MP8659900 |
TSCA | Yes |
HS Code | 29141990 |
Hazard Class | 3 |
Packing Group | III |
FEMA | 3352 | 4-HEXENE-3-ONE |
EPA chemical information | Information provided by: ofmpub.epa.gov (external link) |
toxicity | GRAS(FEMA). |
use limit | FEMA: soft drinks, cold drinks, candy, baked goods, jelly, pudding, gum sugar, seasoning, meat products, meat soup, milk, dairy products, cereal products, all 1.0 mg/kg. |
use | GB 2760-1996 specified as allowed food spices. |
Production method | It is formed by hydration of 4-hexene-2-yne in H2SO4-HgSO4 aqueous solution. It is produced by the catalytic hydrogenation of 2-hexene-5-acetyl-4-one in methanol with Pd-CaCO3 as a catalyst. |